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The mechanism for the formation of ethyl ethanoate
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As a novel strategy, blended alcohols consisting of methanol and ethanol were used as acyl acceptors for biodiesel synthesis from soybean oil by lipase-catalyzed transesterification. Based on enzyme screening, Novozym 435 from Candida antarctica was selected for the reaction. The effects of the molar proportion of methanol in the blended alcohol, temperature, and enzyme loading were investigated for optimization of the reaction. In addition, the relative consumption rates of methanol and ethanol during the transesterification were studied. Among six proportions tested, 0 (100 mol% ethanol), 20, 40, and 60 mol% methanol in the blended alcohols exhibited high yields of biodiesel. For the optimum temperature, 30 °C was selected. The highest yield of biodiesel, over 95 wt%, was obtained at an enzyme loading of 5-10 wt% loading. In the lipase-catalyzed transesterification, the reactivity of methanol was significantly higher than that of ethanol.
Now a molecule of water is lost from the ion.
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JO - Journal of Molecular Catalysis B: Enzymatic
CSI-Bengaluru chapter was established in 2016 by eminent catalysis scientists from various research organizations in Bengaluru like Poornaprajna Institute of Scientific Research, SABIC, SHELL, HPCL, JNCASR, St. Joseph College, IISc and Jain University. The Society is actively working on promoting research in the area of catalysis and bringing together researchers from academia and industry on one platform in Bengaluru by conducting conferences, meetings, workshops, invited talks etc.
N2 - As a novel strategy, blended alcohols consisting of methanol and ethanol were used as acyl acceptors for biodiesel synthesis from soybean oil by lipase-catalyzed transesterification. Based on enzyme screening, Novozym 435 from Candida antarctica was selected for the reaction. The effects of the molar proportion of methanol in the blended alcohol, temperature, and enzyme loading were investigated for optimization of the reaction. In addition, the relative consumption rates of methanol and ethanol during the transesterification were studied. Among six proportions tested, 0 (100 mol% ethanol), 20, 40, and 60 mol% methanol in the blended alcohols exhibited high yields of biodiesel. For the optimum temperature, 30 °C was selected. The highest yield of biodiesel, over 95 wt%, was obtained at an enzyme loading of 5-10 wt% loading. In the lipase-catalyzed transesterification, the reactivity of methanol was significantly higher than that of ethanol.
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T2 - Journal of Molecular Catalysis B: Enzymatic
This symposium aims for disseminating knowledge on the recent discoveries in the field of catalysis encompassing energy, environment and chemicals. There will be an exclusive timing earmarked for Poster session, in order to have thoughtful scientific interactions. The detailed schedule will be made available soon on the new symposium website.
JF - Journal of Molecular Catalysis B: Enzymatic
The Catalysis Society of India (CSI) was formally founded in March 1973 at Varanasi with Prof. S.K. Bhattacharyya as the president and Prof. J.C. Kuriacose as the secretary. The main mandates of the CSI are to encourage catalysis research in India, to organize professional meetings between researchers, to enhance mutual interactions and to encourage cooperation between industry and academia. The growth of the membership of the CSI is a measure of the growth of catalysis research activity in the country. The present membership of the society is more than 750 compared to 75 in 1974. At the time of the founding of the CSI, the major centers of research in catalysis were just a handful, the IITs (Madras and Kharagpur), PDIL (Sindhri), IIP (Dehradun) and IPCL/RIL (Vadodara). Catalysis research activity has spread to many more organizations during the past 42 years. During the last three decades, the catalysis community in India has made significant strides both in applied and fundamental research. Many catalysts and processes has been developed and commercialized, notably by IIP, PDIL, IPCL/RIL, NCL, IICT and ACC in petroleum refining, petrochemicals manufacture, fertilizers production and fine chemicals syntheses. In basic research also, members of the CSI have made significant discoveries in catalysis, resulting in publications in prestigious journals such as Nature, Science, Angew Chem and JACS.
synthesis of biodiesel | Biodiesel | Catalysis
The symposium will include plenary / invited talks by eminent international speakers and highly acclaimed national speakers from industry, academia and research institutions. The symposium would like to give a great deal of importance to research students who will be given sufficient opportunity to present their research outcome through Oral/Poster presentations. It is proposed to have three parallel sessions on various topics mentioned.
Synthesis of biodiesel via acid catalysis
In this backdrop, the symposium plans to bring together the researchers in academia and industry to cover the following broad spectrum of topics encompassing heterogeneous catalysis, homogeneous catalysis, photocatalysis, electrocatalysis, organocatalysis and biocatalysis.
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