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Synthesis of carbon nanotubes from waste polyethylene plastics ..
8.3.3 Mutagenicity in urine The mutagenicity of urine from persons exposed to PAH has been assayed in a number of studies by Ames' test with Salmonella typhimurium TA98 or TA100, with and without metabolic activation.
PAH are extracted from a sample (Lee et al., 1981; Santodonato et al., 1981; Grimmer, 1983a; Griest & Caton, 1983) with: - a Soxhlet apparatus, from filters loaded with particulate matter, vehicle exhausts, or sediments; - directly by liquid-liquid partition, for water samples; or - after complete dissolution (e.g.
Plastics and Organic Synthesis - SIBUR Int
In addition, the hydrophobic Sephadex LH-20 has been found to be suitable for isolating PAH from nonaromatic, nonpolar compounds, which is important if the sample is analysed by gas chromatography (Grimmer & Böhnke, 1979a); It has also been used in partition chromatography as a carrier of the stationary phase, to separate PAH from alkyl derivatives (Grimmer & Böhnke, 1979b).
Therefore, efficient extraction from the sample matrix is usually followed by one or more purification steps, so that the sample to be analysed is as free as possible from impurities and interference.
SIBUR is the largest Russian manufacturer of a wide range of plastics
Peak identification, which is done routinely from data on retention, must be confirmed by analysing samples on a different gas chromatographic column, by an independent technique, such as HPLC, or by directly coupling a mass spectrometric detector to the gas chromatograph (Lee et al., 1981; Olufsen & Bjorseth, 1983; Bartle, 1985; Hites, 1989).
(1942) kk From review by Bjorseth (1983); original references cited by White (1986) ll Temperature not given; reported by Sims & Overcash (1983) mm Calculated by National Toxicology Program (1993) nn Temperature not given; unpublished result cited by Wise et al.
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Biorefineries - Essential Chemical Industry
(1953) bb From IARC (983) cc From Kruber & Grigoleit (1954) dd From Ehrlich & Beevers (1956) ee Reported by Grimmer (1983a) ff From Beilstein Institute for Organic Chemistry (1993) gg Reported by Sims & Overcash (1983) hh Calculated by Yalkowsky & Valvani (1979) ii Calculated by White (1986) jj From Davis et al.
The Essential Chemical Industry Online - Ammonia
Numerous PAH were detected in the final effluent from a Norwegian ferro-alloy smelter in which the wastewater from gas scrubbers was treated by chemical flocculation.
Synthesis of Metal-Organic Frameworks (MOFs): Routes …
(1971); from US Environmental Protection Agency (1980) n From Mackay & Shiu (1981) o When pure, colourless with violet fluorescence; from Budavari (1989) p From Hawley (1987) q From National Institute for Occupational Safety and Health and Occupational Safety and Health Administration (1981) r From Kruber & Marx (1938) s Calculated by Karcher et al.
Chemistry and Biochemistry Courses
(c) Emissions to the geosphere (i) Motor vehicle traffic PAH were deposited within 100 m of a highway at a concentration of 100-200 µg/km per vehicle per day in winter as small particles of dust resulting from the abrasion of asphalt by steel-studded tyres (Lygren et al., 1984).
AQA | Chemistry | Subject content | Organic chemistry
Depending on the matrix, PAH are extracted from samples with a Soxhlet apparatus, ultrasonically, by liquid-liquid partition, or, after sample dissolution or alkaline digestion, with a selective solvent.
polymers properties uses of plastics - Doc Brown
The annual contribution of PAH to landfill in the United Kingdom from fly ash from coal combustion (see also Table 16) exceeded that from municipal solid-waste incineration by a factor of about 10, with the exception of naphthalene, the level of which was about 20 000-fold higher in fly ash from coal combustion than in that from solid-waste incineration.
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