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Synthesis Specialised Software Development
Anyway, that’s probably enough pontification for one blog post, so here are a few of my favourite syntheses and a few that came up in recent conversations—please add yours and your thoughts in the comments!
Paul Dochety's blog at was a massive inspiration to me in my early days as a blogger, showing me that there was enough of a synthetic organic chemistry community online to make writing seemingly very esoteric posts on a small, specialised sub-field rewarding and worthwhile. A couple of years ago, Paul moved away from the online community, but continued his excellent monthly column for the RSC's (think British C&EN, if you're not familiar with it). However, his tenure there has recently also , and to try to fill the organic-shaped hole in its opinion pages the RSC has commisioned a new column – Organic Matter. As you've probably , authorship will be shared between myself, Karl Collins (of ) and the legendary Chemjobber (anyone who needs a should really rethink their blog-reading priorities).
Total Syntheses from A to Z - Organic chemistry
Join Didi for one or both of these sessions, directed towards deepening our self-awareness, connecting with others, and stepping with firm feet into whatever path is calling us. The day will be all psychosynthesis, from presence, to purpose, to will and we will live the maps and practices we all know and love at deeper levels, through the lens of our own beings.
These two workshops invite a deep dive into the psychological functions map. Yay Star Diagram!
The sessions are only for people who are psychosynthesis trained. We will all refine the art of being.
Our first session will involve creating a collage as a way of accessing intuition, trusting impulse and allowing imagination to give us guidance. This outcome will be built around a number of processes, including all the stuff you love in psychosynthesis, including being a group, journeying together!
Our second session will explore the integration of body, mind and feelings, while also knowing each as its own puzzle piece. There will be movement! And Thinking! And Feelings! And the quiet mind, fluid body and sweet feeling worlds will come together.
(For those that need it, the day will be set up to meet BCC continuing education credits with a certificate of Training in the Psychological Functions).
Come for one or both. $250 per day or $450 for both! Please register with !
That's right, for the first time in three and a half years' blogging I find myself writing about that rarest of publications: the collaborative total synthesis. Also somewhat unusually, the two US-based groups involved in the collaboration are both headed up by professors who originally hail from outside the States.
Synthesis Agri-Food Network | Strategy. Action. Results.
I’ve long wanted to write something about maocrystal V total synthesis, but I’ve always been too busy around the time that people have completed it to get a blog post out reasonably close to the event. Fortunately, two back-to-back syntheses from the Zakarian and Thomson groups were published in J. Am. Chem. Soc. earlier this month and I’ve now got plenty time to write about both of them, starting with that of the Thomson group in this post.
I'd initially planned to write about the most recent 2 (or possibly all 3) syntheses in an epic all-in-one comparison blog-post, but in the interests of keeping these musings short and somewhat readable I've decided to break things down a bit. This week's installment will cover Sorenson's awesome synthesis from back in April.
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Maoecrystal V—as the advanced nature of its final letter implies—is one of a great many unusual terpinoids from the Chinese flowing plant Isodon eriocalyx. It possesses a rather intricate and complex structure, a fact illustrated by the two decades that passed between its (first) isolation in 1994 and the successful determination of its structure in 2004—a long period indeed with modern spectroscopic techniques. Its dense, cage-like structure proved a tough nut to crack and another 5 years passed before the deluge of synthetic publications for this target began in 2009. The first total synthesis, reported somewhat controversially by the Yang group the following year, has only seemingly intensified the attention that it has received.
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As the name implies, crotogoudin is another natural product from the goldmine of bioactive compounds that is the Croton genus of flowering trees. Seeds of these plants have been used for hundreds of years to produce the famous , a violent emetic and purgative used in early medicine across the globe before anyone realised just how bad it really was. Now, the notorious extract is mostly used as a source of various natural products, a reproducible way of inducing pain and/or irritation in animal experiments and a case in point that things described as 100% natural can still be extremely bad for you. It also serves as the major source of the important natural product , and gave its name to crotonic and tiglic acid (and thus crotonaldehyde). Along with a number of other natural products isolated from this genus, crotogoudin displays promising cytotoxic activity, which, coupled with the rare 3,4-seco atisane skeleton, was probably one of the reasons that the Carreira group recently embarked on its total synthesis.
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