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Role played organometallic compounds
Alcohol oxidation is important in living organisms. Enzyme-controlled oxidation reactions provide the energy cells need to do useful work. One step in the metabolism of carbohydrates involves the oxidation of the secondary alcohol group in isocitric acid to a ketone group:
Although the participating compounds are complex, the reaction is the same: elimination of water from the starting material. The idea is that if you know the chemistry of a particular functional group, you know the chemistry of hundreds of different compounds.
Homochiral metal–organic coordination networks from L-typtophan
Our research program in organic and organometallic chemistry encompasses synthetic organic, synthetic organometallic, and physical organometallic chemistry. Research goals include discovery of new reactions and catalysts, development of synthetic methods, new techniques for asymmetric synthesis, determination of reaction mechanisms, synthesis of bioactive natural products and development of organometallic complexes for materials research. The development of new chemistry using organometallic species is a rich and fertile area due to the unique ability of transition metal fragments to impart special reactivity, selectivity, and stability upon bonded organic moieties. Our research draws on these features to address problems in organic synthesis.
Chemical reactions in alcohols occur mainly at the functional group, but some involve hydrogen atoms attached to the OH-bearing carbon atom or to an adjacent carbon atom. Of the three major kinds of alcohol reactions, which are summarized in , two—dehydration and oxidation—are considered here. The third reaction type—esterification—is covered in , .
Nanoporous, interpenetratedmetal-organic diamondoid networks
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Inquiries from enthusiastic and motivated students interested in various areas of organic chemistry and catalysis are always welcome.
Synthesis of Alcohols
Alkenes react with water, in the presence of acid, to yield alcohols. The mechanism follows Markovnikov addition. Alkyl halides react with hydroxide to produce alcohols. Organolithium or Grignard reagents add to aldehydes and ketones to produce alcohols. Hydrogen, from sodium borohydride, lithium aluminum hydride, or hydrogen, adds to aldehydes and ketones to produce alcohols.
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Organic chemistry | Science | Khan Academy
Electrochemical tandem synthesis of oximes from alcohols using KNO3 as the nitrogen source, mediated by tin microspheres in aqueous medium
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