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Bonded facilities are available for goods going outside of the EU.

103. L-t-Leucine Catalyzed Direct Asymmetric Aldol Reaction of Cyclic Kentones.
Kanemitsu, T.; Umehara, A.; Miyazaki, M.; Nagata, K.; Itoh, T.
Eur. J. Org. Chem. 2011, 993-997.

Our Regulatory Team and Quality Control Departments are based out of Carterton.

Sigma-Aldrich also provides a suite of analytical tools that allow food analysts to simplify sample preparation, cleanup and analysis steps, while increasing sensitivity to trace ingredients and harmful substances to meet regulations and quality standards.

172.515 Synthetic flavoring substances and adjuvants.

116, 1979.

oral-rabbit LD50 145 mg/kg
"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol.

100, 1982.

intravenous-rabbit LDLo 160 mg/kg
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLDLUNGS, THORAX, OR RESPIRATION: DYSPNEAPERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
Japanese Journal of Medical Sciences, Part 4: Pharmacology.

Labor Hygiene and Occupational Diseases.

128, 1933.

unreported-frog LDLo 1750 mg/kg
PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGELUNGS, THORAX, OR RESPIRATION: DYSPNEA
"Structure et Activite Pharmacodyanmique des Medicaments du Systeme Nerveux Vegetatif," Bovet, D., and F.

95, 1962.

subcutaneous-rabbit LD50 300 mg/kg
LUNGS, THORAX, OR RESPIRATION: DYSPNEAPERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGEBEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Japanese Journal of Medical Sciences, Part 4: Pharmacology.

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Toxicology of New Industrial Chemical Substances.

Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes.

For English translation, see TNICS*.

114. Phase-transfer Catalyzed Sulfenylation of 3-Substituted-2-oxindoles.
Nagata, K.; Sano, D.; Aoyama, O.; Kanemitsu, T.; Miyazaki, M.; Odanaka, Y.; Machida, A.; Itoh, T.
Heterocycles, 2016, 92, 631-635

Pyridine synthesis - Organic chemistry

113. A Concise One-pot Organo- and Biocatalyzed Preparation of Enantiopure
Hexahydrofuro[2,3-b]furan-3-ol: An Approach to Synthesis of HIV Protease Inhibitors.
Kanemitsu, T.; Inoue, M.; Yoshimura, N.; Yoneyama, K.; Watarai, R.; Miyazaki, M.; Odanaka, Y.; Nagata, K.; Itoh, T.
Eur. J. Org. Chem. 2016, in press.

Saturated compound synthesis by reduction of …

112. Recent Progress of Fluorescent Probes for the Detection of Nitric Oxide in Biological Systems.
Nagata, K.; Itoh, T.
Journal of The Showa University Society 2015, 75, 168-176.

Knorr pyrrole synthesis - Wikipedia

111. Application of Asymmetric Alkylation of Malonic Diester with Phase-transefer Catalysis: Synthesis of LFA-1 Antagonist BIRT-377.
Kanemitsu, T.; Furukoshi, S.; Miyazaki, M.; Nagata, K.; Itoh, T.
Tetrahedron: Asymmetry 2015,26, 214-218.

List of Publications (1990年以降) 114

110. Asymmetric Synthesis and Catalytic Activity of 3-Methyl-β-proline in Enantioselective anti-Mannich-type Reactions.
Nagata, K.; Kuga, Y.; Higashi, A.; Kinoshita, A.; Kanemitsu, T.; Miyazaki, M.; Itoh, T.
J. Org. Chem. 2013,78, 7131-7136.

Phase-transfer Catalyzed Sulfenylation of 3-Substituted-2-oxindoles

109. Development of Organocatalytic Asymmetric Reactions and Their Application to the Syntheses o f Synthetically Usefull Compounds.
Kanemitsu, T.; Itoh, T.
The Showa University Journal of Pharmaceutical Sciences 2012, 3, 129-144.

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