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Metal-Mediated Bond Forming Processes in Synthetic Organic Chemistry

Current research centers around organometallic chemistry, and branches into catalysis, organic synthesis, enantioselective reactions, stereochemistry, mechanism, and materials and green chemistry. Present initiatives include enantioselective and recoverable catalysts, and organometallic building blocks for molecular wires and gyroscopes.

 Medicinal chemistry, organofluorine and carbohydrate chemistry, synthetic methodology

Methodology. Here our focus is on developing tools to enable synthetic transformations to be performed in an efficient manner. This includes the discovery, development and exemplification of new transformations; the optimisation and scoping of existing transformations (e.g. by developing new reagents or catalysts) and the creation of novel molecular architectures such as scaffolds for drug development. Results from this type of research feed into, or are directly connected with, our interests in total synthesis and medicinal chemistry.

25th International Symposium: Synthesis in Organic Chemistry

Other Main Group Organometallic Reagents

Current research centers around organometallic chemistry, and branches into catalysis, organic synthesis, enantioselective reactions, stereochemistry, mechanism, and materials and green chemistry. Present initiatives include enantioselective and recoverable catalysts, and organometallic building blocks for molecular wires and gyroscopes.

Because atoms do not spontaneously lose electrons, energy is required to remove an electron from an atom to form a cation. Chemists define the of an element as the amount of energy needed to remove an electron from the gaseous atom E in its ground state. I is therefore the energy required for the reaction

are becoming increasingly prevalent in organic synthesis

The areas of organic synthesis, new organic reactions, ..

Total synthesis. Research is focused on exploring strategies for the efficient construction of target compounds. In many cases, judicious selection from the existing ‘toolbox’ of organic transformations is key, but at times novel transformations need to be developed to address a particular structural feature.

Medicinal chemistry. In Southampton this covers a wide range of research, typically directed at the optimisation of properties through introducing changes in the molecular structure of ‘lead’ compounds (the synthesis of analogues). For the most part it is centred on the optimisation of bioactivities, but also includes metabolic stability and lipophilicity. In fact, the study of the change in molecular properties upon introduction of a particular modification (e.g. fluorination) can be a goal in itself. Medicinal chemistry oriented research is typically conducted in collaboration with biological scientists, in academia and industry, who are interested in exploiting bioactive compounds.

Discover more about our Research Group that specialise in Organic Chemistry: Synthesis, Catalysis and Flow at the University of Southampton
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Synthesis of Metal-Organic Frameworks (MOFs): …

Synthetic organic chemists look to make molecules that have an interesting function, whether this be biological activity (natural products, drugs, drug-like compounds, agrochemicals, diagnostics, probes etc.) or materials with useful properties (liquid crystals, organic electronic materials etc.). Importantly, some of our targets are known molecules while others are newly designed ones. As a consequence, we often work together to solve problems that demand a broad range of expertise.

Abstracts of Articles on Organic Synthesis

Inorganic and materials chemistry, focusing on design and synthesis of metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs) applied to energy-related research (e.g., CO2 capture, H2 storage), catalysis, and biomedical applications.

Ester synthesis by esterification - Organic chemistry

Organometallic and inorganic synthesis for the development of new strategies for oxidation chemistry. Investigation of the structures of reactive intermediates and the effects of confinement and proximity on organic reactions.

25th International Symposium: Synthesis in Organic …

Organometallic and inorganic synthesis for the development of new strategies for oxidation chemistry. Investigation of the structures of reactive intermediates and the effects of confinement and proximity on organic reactions.

Inorganic chemistry - Wikipedia

Studies in molecular transition metal and main group chemistry. Ligand design for novel elementary transformations and catalysis, with recent emphasis on borylation chemistry. Exploration of the frontiers of synthesis and reactivity of highly reactive cations and most weakly coordinating anions. New materials based on metallopolymers with redox-active ligands.

Synthesis - Mark Moloney Research Group

Because the tendency of an element to gain or lose electrons is so important in determining its chemistry, various methods have been developed to quantitatively describe this tendency. The most important method uses a measurement called (represented by the Greek letter chi, χ, pronounced “ky” as in “sky”), defined as the relative ability of an atom to attract electrons to itself in a chemical compound. Elements with high electronegativities tend to acquire electrons in chemical reactions and are found in the upper right corner of the periodic table. Elements with low electronegativities tend to lose electrons in chemical reactions and are found in the lower left corner of the periodic table.

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