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Organic chemistry: SN2 and SN1 reactions
Organic chemistry: “Introduction to Grignard reagents”. Reaction of Grignard reagents as bases with solvents. Reaction of as with and . Introduction to synthesis with .
Organic chemistry: “”. of alcohols (PBr3, SOCl2). (, alkyl , ). Using the technique to solve synthesis problems involving (Gilman reagents).
Organic chemistry: “More on SN2, SN1, E2, and E1 reactions”
Designing an organic synthesis Learn Chemistry Wiki Master Organic Chemistry Chemistry Services including drug discovery services and basic pharmacology
Organic chemistry: “Electron-pushing arrows”. How to use electron-pushing arrows, also known as “curved arrows,” to draw intermediates and products in reaction mechanisms.
Organic chemistry: “Retro Diels-Alder reaction”.
Organic chemistry: “ of alkenes”. addition reactions. Addition of OsO4 (osmium ) to achieve . Using to achieve anti . A synthesis problem. The synthetic toolbox. When does hindrance block one face of a planar intermediate?
Organic chemistry: “Hydrogenation and ”. addition reactions. Problems involving degrees of and hydrogenation (addition of H2). E/Z naming of alkenes. Problems involving addition of X2 (). Forming alkenes from alcohols via E1 (dehydration with H2SO4) or E2.
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Acetoacetic-Ester Synthesis - Organic chemistry
Organic chemistry: “ synthesis and reactions”. of carbons; acidity of alkynes; use of anions as for SN2 reactions and for attack on (). synthesis from by double elimination; synthesis from alkenes by -double . reactions. Hydrogenation of alkynes; hydrogenation of with catalyst to form alkenes; sequential one-electron reduction of alkynes with sodium metal to form trans alkenes. addition of HX to alkynes; addition of X2 to alkynes (). ; ; mercuric ion-catalyzed hydration of alkynes to form
Acetoacetic-Ester Condensation Claisen Condensation
Organic chemistry: “ aromatic substitution”. aromatic substitution of benzene. Substitution through intermediates. Summary of methods for synthesis of phenols. oxidation to carboxylic acids; synthesis problems involving oxidation. Radical
Acetoacetic Ester Condensation - Organic chemistry
Organic chemistry: “Alkenes: addition of , BH3, X2”. addition reactions. Addition of H2 (hydrogenation). Addition of , with or without peroxides. Addition of BH3 to get alcohols (-oxidation). Addition of X2.
acetoacetic ester synthesis Acetoacetic ester is …
Organic chemistry: “More on and ”. attack on and ; the three main categories of attack. Two category 1 reactions: attack by a Grignard to form an alcohol; attack by LAH to form an alcohol. A category 2 reaction: attack by alcohol in acidic conditions to form an or . A category 2 “reverse” reaction: reaction of an or with aqueous acid to form an or
21.6 The Acetoacetic Ester Synthesis - [PPT Powerpoint]
Organic chemistry: “Addition to alkenes: H2, HX, H2O”. addition reactions. Addition of H2 (hydrogenation). additions: addition of HX (); addition of H2SO4, H2O (hydration); addition of H2SO4, ROH. Addition of HX in presence of ROOR (radical addition using peroxide initiator). : vs. anti-
21.6 The Acetoacetic Ester Synthesis
Organic chemistry: “Carboxylic acids and acid derivatives”. Acidity of carboxylic acids; ranking compounds in order of acidity. How to synthesize carboxylic acids: oxidation; carbonation; hydrolysis. The types of carboxylic acid derivative. The general pattern for attack on carboxylic acids and acid derivatives (addition-elimination). . Ranking carboxylic acids derivatives in order of reactivity
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